Preparation of linear alpha-olefins by a modified chain...

Details Preparation of linear alpha-olefins by a modified chain... Preparation of linear alpha-olefins by a modified chain...

C - Chemistry, Metallurgy

07

C

C07C 11/02 (2006.01) C07C 2/88 (2006.01)

Patent

CA 2103100

Abstract Linear alpha-olefin products which are enriched in one or more olefins of a selected carbon number are prepared by an ethylene chain growth process startingwith a trialkylaluminum compound represented by the formula AlR3, in which each R group contains 3 to 10 carbon atoms, adding an average number of ethylene units to the R groups so as to form aluminum alkyls which are enriched in R groups having the selected carbon number, recovering the alpha-olefin products from the aluminum alkyls by catalyzed alkyl displacement, and recycling the trialkylaluminum product of the displacement to the chain growth reaction.

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