Preparation of maleic anhydride from four-carbon hydrocarbons

C - Chemistry – Metallurgy – 07 – D

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C07D 307/60 (2006.01) B01J 21/06 (2006.01) B01J 27/18 (2006.01) C07C 51/215 (2006.01) C07C 51/25 (2006.01)

Patent

CA 1089479

PREPARATION OF MALEIC ANHYDRIDE FROM FOUR-CARBON HYDROCARBONS ABSTRACT OF THE DISCLOSURE Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

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