Preparation of organopolysiloxanes with si-c bonded ester...

C - Chemistry – Metallurgy – 07 – F

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253/136, 8/93.21

C07F 7/08 (2006.01) C08G 77/04 (2006.01) C08G 77/14 (2006.01) C08G 77/38 (2006.01) C10M 107/50 (2006.01)

Patent

CA 1121827

ABSTRACT OF THE DISCLOSURE Organoslloxanes are provided herein which have SiC-bonded ester groups and contain at least one unit of the general formula: Image in which R represents the same or different monovalent hydro- carbon radicals having from 1 to 12 carbon atoms, which are free of aliphatic unsaturation and which may contain one ether oxygen atom; R' represents hydrogen or a methyl group (CH3) and a is O, 1 or 2. These organosiloxanes can be prepared by hydrolyzing or co-hydrolyzing silanes of the general formula: ROOCCH2CH)COOR)CH2CHR'CH2Si(CH3)aX3-a, where R, R' and a are the same as above and X represents the same or different hydrolyzable atoms or groups. Also, they may be prepared by the addition of a diester of allyl succinic acid and/or methallyl succinic acid to an organoslloxane containing Si-bonded hydrogen. These new organosiloxanes may be used as lubricants for inorganic and organic fibers, metal surfaces and as hydraulic fluids.

322901

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