Preparation of ortho-(alkylthiomethyl)anilines by catalytic...

C - Chemistry – Metallurgy – 07 – C

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260/601.2

C07C 149/273 (1985.01)

Patent

CA 1218079

PREPARATION OF ORTHO-(ALKYLTHIOMETHYL) ANILINES BY CATALYTIC SULFILIMINE REARRANGEMENT ABSTRACT This invention relates to a process for preparing ortho (alkylthiomethyl) anilines by catalytic rearrangement of aromatic sulfilimines in an inert organic solvent. The sulfilimine can be pre- pared using any of the procedures available in the art. This invention particularly relates to a new class of sulfilimine rearrangement cata- lysts.

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