Preparation of polyalkylated cyclopentadienes from isobornyl...

C - Chemistry – Metallurgy – 07 – C

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C07C 13/15 (2006.01) C07C 1/207 (2006.01) C07C 1/213 (2006.01) C07C 2/86 (2006.01) C07C 5/27 (2006.01)

Patent

CA 2170460

A process for preparing tetraalkylated cyclopentadienes comprises (a) pyrolyzing a isobornyl carboxylate so as to form a mixture of 1,2,3- and 1,2,4-trimethyl- cyclopentadienes, (b) alkylating said mixture with an alkylating agent so as to form a mixture of alkyltrimethylcyclopentadiene isomers including 1,2,3,4-alkyltrimethyl- cyclopentadiene and, (c) thermally isomerizing the mixture of isomers obtained in step (b) so as to increase the proportion of 1,2,3,4-alkyltrimethylcyclopentadiene in said mixture of isomers.

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