C - Chemistry – Metallurgy – 08 – K
Patent
C - Chemistry, Metallurgy
08
K
402/359
C08K 5/34 (2006.01) C08G 65/44 (2006.01)
Patent
CA 1204248
Abstract of the Disclosure: A process for the prepara- tion of high molecular weight polyphenylene ethers from monohydric phenols which have alkyl substituents in both ortho-positions and may additionally have an alkyl sub- stituent in one meta-position but not in the para-position, by an oxidative coupling reaction, employing oxygen, at from 10 to 25°C, in the presence of a catalyst complex comprising a copper salt and an N-substituted imidazole, in the presence of an aromatic C8-C10-hydrocarbon solvent. N-Methylimidazole, N-ethylimidazole, N-isopropyl- imidazole, N-n-butylimidazole, N-cyclohexylimidazole, N-octylimidazole and N-phenylimidazole are preferably used as the imidazole, advantageously in amounts of from 0.5 to 5 percent by weight.
406895
Hambrecht Juergen
Naarmann Herbert
Rieber Norbert
Basf Aktiengesellschaft
Robic Robic & Associes/associates
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