Preparation of silane from amine alanes

Details Preparation of silane from amine alanes Preparation of silane from amine alanes

C - Chemistry, Metallurgy

01

B

23/166, 23/196

C01B 33/04 (2006.01) C01F 7/50 (2006.01)

Patent

CA 1212515

PREPARATION OF SILANE FROM AMINE ALANES Abstract of the Disclosure A process for the coproduction of silane and AlF3 is described. SiF4 and amine alane (AlH3 NR3) complexes are reacted to produce gaseous silane and AlF3 coproduct. The amine tends to complex somewhat with coproduct AlF3 but is released therefrom by heating. AlF3 is a very saleable commodity thereby making the invention an improvement over other hydride reactions which produce less usable coproducts.

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