Preparation of tertiary butyl alcohol by catalytic...

C - Chemistry – Metallurgy – 07 – C

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C07C 31/12 (2006.01) C07C 29/132 (2006.01)

Patent

CA 2135558

PREPARATION OF TERTIARY BUTYL ALCOHOL BY CATALYTIC DECOMPOSITION OF TERTIARY BUTYL HYDROPEROXIDE (Docket No. 81,236-F) ABSTRACT OF THE DISCLOSURE A method for preparing tertiary butyl alcohol wherein feedstock comprising a solution of tertiary butyl hydroperox- ide in a cosolvent mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydro- peroxide decomposition catalyst and is brought into contact with the catalyst in liquid phase with agitation under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.

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