Preparation of unsaturated aldehydes from propargyl alcohol...

C - Chemistry – Metallurgy – 07 – C

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C07C 47/38 (2006.01) C07C 45/51 (2006.01) C07C 45/69 (2006.01) C07C 47/42 (2006.01) C07C 47/45 (2006.01) C07C 47/46 (2006.01)

Patent

CA 2269451

Unsaturated aldehydes are prepared by mixing propargyl alcohol, a catalyst and a conjugated diolefin and heating the mixture for a time and at a temperature sufficient to form an unsaturated aldehyde. The diolefin may be 2-methylpentadiene, 2-(5,5- dimethyl- 5-hydroxy-pentyl)-1,3-butadiene or myrcene. The catalyst may be inorganic, organic, organometallic or mixtures thereof.

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