Preparation process of functionalized amine diene polymer,...

C - Chemistry – Metallurgy – 08 – F

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C08F 136/04 (2006.01) C08C 19/44 (2006.01) C08F 4/48 (2006.01) C08F 4/52 (2006.01) C08F 8/32 (2006.01) C08F 36/04 (2006.01) C08F 236/10 (2006.01) C08F 236/14 (2006.01) C08J 3/24 (2006.01)

Patent

CA 2294580

Process for preparing amino functionalized diene polymers with 1,4-trans linkage content equal to or greater than 70%. The invention also concerns polymers of such type, a rubber composition and a tire casing containing those polymers. The process of preparation according to the invention comprises polymerizing at least one diene monomer by means of a lithium catalytic system, which comprises at least one hydrocarbon solvent, one compound A of a IIIA group metal, one compound B of an alkaline earth metal and one aminolithium initiator C. A rubber composition vulcanizable with sulfur according to the invention is such that it contains at least said polymer. A tire casing according to the invention is such that it contains said composition.

Procédé de préparation de polymères diéniques fonctionnalisés amine, et à teneur en enchaînements 1,4-trans qui est égale ou supérieure à 70 %. L'invention concerne également de tels polymères, une composition de caoutchouc et une enveloppe de pneumatique comportant ces polymères. Le procédé de préparation consiste à polymériser au moins un monomère diénique à l'aide d'un système catalytique lithié, lequel est constitué d'au moins un solvant hydrocarboné, d'un composé A d'un métal du groupe IIIA, d'un composé B d'un métal alcalino-terreux et d'un initiateur C amino-lithié. Une composition de caoutchouc vulcanisable au soufre selon l'invention est telle qu'elle comporte au moins ledit polymère. Une enveloppe de pneumatique selon l'invention est telle qu'elle comporte ladite composition.

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