Procedure for the preparation of organolithium compounds...

Details Procedure for the preparation of organolithium compounds... Procedure for the preparation of organolithium compounds...

B - Operations, Transporting

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23/294, 260/361,

B01J 31/12 (2006.01) B01J 31/16 (2006.01) C07D 339/04 (2006.01) C07D 495/04 (2006.01) C07F 1/02 (2006.01) C07F 7/08 (2006.01)

Patent

CA 1148924

ABSTRACT OF THE DISCLOSURE A catalytic system is provided for the lithiation of .alpha.-olefins and .alpha.,.omega.-diolefins with concurrent production of lithium hydride. The catalysts include oxygen and sulfur containing organic compounds and polycyclic aromatics which can be combined with alkali metals and/or transition metal compounds. High yields of pure and stereospecific lithiated olefins are obtainable.

347087

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