Process and apparatus for polymerisation catalyst development

C - Chemistry – Metallurgy – 07 – B

Patent

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Details

C07B 61/00 (2006.01) B01J 19/00 (2006.01) C08F 2/00 (2006.01) G01N 30/12 (2006.01) G01N 31/10 (2006.01) G01N 35/00 (2006.01)

Patent

CA 2384703

Process for selecting at least one combination among the possible combinations from a group of polymerization catalysts and from a group of sets of polymerization conditions according to the targeted values of one or more properties Pi of the resulting polymers, which process is characterized in that, for each combination, each polymer is subjected to analysis by gas chromatographic pyrolysis and, from the results of the analysis, at least one property Pi of the polymer is evaluated by virtue of correlations drawn up beforehand between the property or properties Pi of the polymers and the results of the analysis of the said polymer by gas chromatographic pyrolysis and, in that the combination or combinations corresponding to the desired value of the property or properties Pi is/are selected.

L'invention concerne un procédé pour sélectionner au moins une combinaison parmi les combinaisons possibles dans un groupe de catalyseurs de polymérisation et un groupe d'ensembles de conditions de polymérisation en fonction des valeurs cibles d'une ou de plusieurs propriétés Pi des polymères finaux; le processus de l'invention est caractérisé en ce que pour chaque combinaison chaque polymère est analysé au moyen de la chromatographie à pyrolyse. Sur la base des résultats de cette analyse, on évalue au moins une propriété Pi du polymère au moyen des corrélations établies préalablement entre la ou les propriétés Pi des polymères et les résultats de l'analyse dudit polymère au moyen de la chromatographie à pyrolyse; on sélectionne ensuite la ou les combinaisons correspondant à la valeur désirée de la propriété (des propriétés) Pi sélectionnée(s).

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