Process and apparatus for recovering hydrocarbons from...

B - Operations – Transporting – 01 – D

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B01D 53/04 (2006.01) B01D 53/047 (2006.01)

Patent

CA 1149308

Abstract of the Disclosure A process and apparatus for recovering hydrocarbons from an air-hydrocarbon vapor mixture such as the mixture of air and vaporized light hydrocarbon compounds expelled as a result of loading gasoline or the like into storage tanks, tank cars and tank trucks. The air-hydrocarbon vapor mixture is caused to flow through a bed of solid adsorbent whereby the hydrocarbons are removed from the mixture and a residue gas stream comprised of substantially hydrocarbon-free air is produced. The substantially hydrocarbon- free air is vented to the atmosphere and a second bed of solid adsorbent having hydrocarbons adsorbed thereon is subjected to conditions which cause desorption of the hydrocarbons and thereby regeneration of the bed. The flow pattern of the inlet air- hydrocarbon vapor mixture and the bed of solid adsorbent being regenerated are periodically changed so that when the bed through which the inlet air-hydrocarbon vapor mixture is flowing becomes loaded with adsorbed hydrocarbons, the inlet air-hydrocarbon vapor mixture is caused to flow through the bed which has just been regenerated. The regeneration of the beds is accomplished by evacuating the beds with vacuum pumping and the air-hydrocarbon vapor mixture produced in the regeneration of the beds is contacted with a liquid absorbent whereby a major portion of the hydrocarbons are absorbed therefrom and recovered. The beds of solid adsorbent are cooled, at least while the air-hydrocarbon vapor mixture is flowing therethrough and hydrocarbons are being adsorbed on the bed, to prevent the beds from overheating due to side exothermic reactions of hydrocarbons and/or impurities contained in the air- hydrocarbon vapor mixture with air and/or the solid adsorbent. Apparatus for carrying out the process of the present invention is also provided.

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