Process and apparatus for treating solutions containing...

C - Chemistry – Metallurgy – 01 – B

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204/165, 204/78.

C01B 4/00 (2006.01) C02F 1/46 (2006.01) G21F 9/06 (2006.01)

Patent

CA 1215020

ABSTRACT OF THE DISCLOSURE The invention relates to a process and to an apparatus for treating solutions containing tritiated water wherein an electrolyte, such as soda, is added to the solution, the solution obtained then undergoes electrolysis in order to release tritium in the gaseous state. Working takes place in an electrolytic cell having a cathode made from a metal which aids the diffusion of tritium, e.g. a Pd-Ag alloy coated with porous palladium black. The cathode forms a separating wall between the solution to be electrolysed and a tritium reception compartment. The tritium which has diffused through the wall of the cathode is recovered in the compartment. Use for the recovery of tritium from effluents resulting from the reprocessing of irradiated nuclear fuels.

417276

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