Process and catalyst for converting synthesis gas to liquid...

C - Chemistry – Metallurgy – 10 – G

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C10G 1/04 (2006.01) B01J 23/76 (2006.01) B01J 29/04 (2006.01) B01J 29/06 (2006.01) B01J 35/10 (2006.01) C07C 1/04 (2006.01) C07C 9/14 (2006.01) C10G 3/00 (2006.01)

Patent

CA 1177464

ABSTRACT OF THE DISCLOSURE Synthesis gas containing CO and H2 is converted to a high-octane hydrocarbon liquid in the gasoline boiling point range by bringing the gas into contact with a heterogeneous catalyst including, in physical mixture, a zeolite molecular sieve, cobalt at 6-20% by weight, and thoria at 0.5-3.9% by weight. The contacting occurs at a temperature of 250- 300°C, and a pressure of 10-30 atmospheres. The conditions can be selected to form a major portion of the hydrocarbon product in the gasoline boiling range with a research octane of more than 80 and less than 10% by weight aromatics.

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