Process and catalyst for dehydrogenating primary alcohols to...

B - Operations – Transporting – 01 – J

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B01J 25/00 (2006.01) B01J 23/72 (2006.01) B01J 23/745 (2006.01) B01J 23/755 (2006.01) B01J 25/02 (2006.01) B01J 37/02 (2006.01) B01J 37/16 (2006.01) B01J 37/34 (2006.01) C07C 51/235 (2006.01) C07C 227/02 (2006.01) C07F 9/38 (2006.01) B01J 23/70 (2006.01)

Patent

CA 2463776

This invention is directed to a process for making a salt of a carboxylic acid. The process comprises contacting a catalyst with an alkaline mixture comprising a primary alcohol. In one embodiment, the catalyst comprises a metal supporting structure (preferably a metal sponge supporting structure comprising at least about 10% by weight nickel) having a copper-containing active phase at the surface thereof and iron as a catalyst modifier. The supporting structure is resistant to deformation under the conditions of the dehydrogenation reaction. This invention is also directed to novel nickel- containing catalysts having a copper-containing active phase and iron as a catalyst modifier which may, for example, be used in the above process. This invention is further directed to processes for making such catalysts.

La présente invention concerne un processus de fabrication d'un sel d'acide carboxylique. Ce processus consiste à mettre en contact un catalyseur avec un mélange alcalin comprenant un alcool primaire. Dans un mode de réalisation de l'invention, le catalyseur comprend une structure de support métallique (de préférence une structure de support de mousse métallique comprenant au moins environ 10 % de nickel en poids) possédant une phase active contenant du cuivre à la surface de celle-ci et du fer comme modificateur de catalyseur. Cette structure de support résiste à la déformation dans les conditions de réaction de déshydrogénation. Cette invention concerne aussi de nouveaux catalyseurs contenant du nickel possédant une phase active contenant du cuivre et du fer comme modificateur de catalyseur qui peuvent, par exemple, être utilisés dans les processus susmentionnés. Cette invention concerne enfin des processus de fabrication de ces catalyseurs.

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