Process and catalyst for dehydrogenating primary alcohols to...

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 51/235 (2006.01) B01J 23/72 (2006.01) B01J 35/04 (2006.01) B01J 37/34 (2006.01) C07C 227/02 (2006.01) C07F 9/38 (2006.01) B01J 23/70 (2006.01) B01J 23/80 (2006.01) B01J 23/835 (2006.01) C07C 229/16 (2006.01)

Patent

CA 2405853

This invention is directed to a process for making a salt of a carboxylic acid. The process comprises contacting a catalyst with an alkaline mixture comprising a primary alcohol. In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) having a copper- containing active phase at the surface thereof. The support is resistant to deformation under the conditions of the dehydrogenation reaction. In another embodiment, the catalyst comprises a metal sponge having a copper-containing active phase at the surface thereof and a supporting structure containing at least 10% non-copper metal. This invention is also directed to copper- containing catalysts which may, for example, be used in the above process. This invention is further directed to processes for making such catalysts.

L'invention concerne un procédé de fabrication d'un sel d'acide carboxylique. Ce procédé consiste à mettre en contact un mélange alcalin contenant un alcool primaire avec un catalyseur. Dans une réalisation, par exemple, le catalyseur est constitué d'un support métallique (de préférence un support en éponge métallique) et, sur sa surface, d'une phase active contenant du cuivre. Le support est résistant à la déformation dans les conditions de la réaction de déshydrogénation. Dans une autre réalisation, le catalyseur est constitué d'une éponge métallique comprenant, sur sa surface une phase active contenant du cuivre et d'une structure de support contenant au moins 10 % de métal sauf du cuivre. L'invention concerne aussi des catalyseurs contenant du cuivre qui peuvent, par exemple, être utilisés dans le procédé décrit ci-dessus. Elle concerne aussi des procédés de fabrication de tels catalyseurs.

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