Process and composition for increasing the reactivity of...

B - Operations – Transporting – 01 – J

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B01J 23/60 (2006.01) B01D 53/86 (2006.01)

Patent

CA 2451655

In ridding fluids, including hydrocarbon fluids, both gaseous and liquid, of sulfur compounds including hydrogen sulfide, oxides of sulfur, and thiols, the present invention uses a small quantity of an activator, generally a noble metal oxide, preferably a copper species and/or a manganese species, along with a known oxide product, such as iron oxide, iron hydroxide, zinc oxide, zinc hydroxide, manganese oxide, manganese hydroxide, or combinations thereof, to thoroughly remove sulfur contaminants in a short amount of time. The activator allows for the use of smaller reactor vessels and the production of hydrocarbon fluids substantially free of sulfur products.

Dans des fluides d'entraînement comprenant des fluides hydrocarbures gazeux ou liquides, renfermant des composés sulfurés tels que sulfure d'hydrogène, oxydes de soufre et thiols, l'invention utilise une petite quantité d'un activateur, généralement, un oxyde d'un métal noble, de préférence du type cuivre et/ou du type manganèse, conjointement avec un oxyde connu tel qu'oxyde de fer, hydroxyde de fer, oxyde de zinc, hydroxyde de zinc, oxyde de manganèse, hydroxyde de manganèse, ou des combinaisons de ces produits, en vue d'éliminer complètement les impuretés sulfurées en un temps très court. L'activateur permet d'utiliser des réacteurs de plus petites dimensions et de produire des fluides hydrocarburés presque totalement débarrassés de produits sulfurés.

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