Process for acetic acid preparation and heterogeneous...

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252/90, 260/529.

B01J 31/18 (2006.01) B01J 31/16 (2006.01) C07C 45/50 (2006.01) C07C 51/12 (2006.01)

Patent

CA 1322193

Abstract of the Invention An improved Monsanto-type process for acetic acid preparation and a heterogoneous-supported catalyst for accomplishing the same, comprising reacting methanol with carbon monoxide under pressure of about 65-80 Bar and temperature of about 170-200° in the presence of methyl iodide and a catalyst comprising an insoluble polymer having pendant free base. N-oxide or quaternized pyridine groups supporting a rhodium species loaded to less than about 10 weight percent (expressed as metal) of the polymer component.

558180

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