Process for alkylating and smiles rearrangement of hydroxy...

Details Process for alkylating and smiles rearrangement of hydroxy... Process for alkylating and smiles rearrangement of hydroxy...

C - Chemistry, Metallurgy

07

J

C07J 41/00 (2006.01) C07C 231/10 (2006.01) C07C 231/12 (2006.01) C07C 235/16 (2006.01) C07D 307/79 (2006.01) C07D 307/91 (2006.01)

Patent

CA 2250066

The present invention is a process of converting a hydroxy aromatic into a 2- hydroxy-N-arylacetamide, comprising: (1) treating a reaction mixture comprising a salt of a hydroxy aromatic with an alkylating agent; and (2) treating the reaction mixture with a Smiles solvent system and raising the temperature of the reaction mixture.

Procédé de conversion d'un aromatique hydroxylé en un 2-hydroxy-N-arylacétamide, consistant à (1) traiter un mélange réactionnel comprenant un sel d'un aromatique hydroxy au moyen d'un agent d'alkylation; et (2) traiter le mélange réactionnel avec un système solvant de Smiles et augmenter la température dudit mélange.

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