Process for catalytically hydrocracking a heavy hydrocarbon oil

C - Chemistry – Metallurgy – 10 – G

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C10G 47/02 (2006.01) C10G 47/12 (2006.01)

Patent

CA 1094004

TITLE A PROCESS FOR CATALYTICALLY HYDDROCRACKING A HEAVY HYDROCARBON OIL INVENTORS Marten Ternan Basil I. Parsons ABSTRACT OF DISCLOSURE A process for catalytically hydrocracking a heavy hydrocarbon oil containing at least 25 weight percent of hydro- carbon substances which will boil at a temperature of at least 524°C and contain coke forming hydrocarbon substances and which may contain hydrocarbon substances with metal present are hydrocracked in a continuous process. The heavy hydrocarbon oil is first slurried at 50°C to 400°C with a particulate catalyst mass comprising aluminum compound coated coal and/or coke parti- cles which may also be coated with a cobalt and/or a molybdenum compound, the slurry is heated to 250°C to 550°C and continuous- ly fed to the bottom of a catalytic hydrocracking vessel to pass upwardly therethrough at a pressure in the range 100 to 3,500 psig and a temperature in the range 400°C to 500°C. The process avoids coking of the reactor vessel and being continuous re- places the catalyst mass before excessive deposits of coke or metals occurs thereon. While cobalt and nickel compounds are preferred, any compounds of metals of Groups VI (b) or VIII of the Periodic Table may be used.

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