Process for causticizing green liquor in chemical recovery...

D - Textiles – Paper – 21 – C

Patent

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D21C 11/04 (2006.01) C01D 1/20 (2006.01) C01F 11/18 (2006.01) D21C 11/10 (2006.01) D21C 11/12 (2006.01)

Patent

CA 2475610

This invention provides an improved process for recovering chemicals from black liquor in alkaline pulping, which is achieved by introducing depuration treatments of green liquor and lime before causticization reaction and a two-step-causticization procedure in the causticization procedure of the conventional chemical recovery process. The process of this invention not only avoids the generation of the waste residue (lime mud) from the beginning and saves the recovery and treatment of lime mud, but also can directly produce a series of precipitated calcium carbonate products with various particle sizes by regulating process conditions while the alkali is recovered, said CaCO3 products including a CaCO3 suitable for making coated paper, wherein >= 50% of the CaCO3 has a particle size below 2µm; a CaCO3 suitable for making neutral sized paper, wherein >= 90% of the CaCO3 have a particle size below 2µm; a superfine CaCO3 having an average particle size < 1µm. The present invention can be used for treatment of pollution of black liquor in the alkaline pulping.

La présente invention se rapporte à un procédé de récupération d'alcalis à partir de la liqueur noire de la fabrication du papier. Le procédé classique de récupération des alcalis est amélioré par ajout de deux étapes consistant en un traitement de la liqueur verte et en une épuration de la chaux, par modification des conditions de traitement, et par mise en oeuvre de deux chaînes de caustification, ceci permettant d'éviter la formation d'une boue de liqueur blanche ainsi que le traitement de ladite boue. Ce procédé permet la production du produit suivant: 50 % en poids ou plus de carbonate de calcium ayant une dimension granulométrique inférieure ou égale à 2 mu m, utilisé dans le papier couché; 90 % en poids ou plus de carbonate de calcium ayant une dimension granulométrique inférieure ou égale à 2 mu m, utilisé pour le collage neutre; et une très petite quantité de carbonate de calcium ayant une dimension granulométrique inférieure ou égale à 1 mu m. La présente invention permet de traiter les contaminants mis en oeuvre pour réduire la liqueur noire dérivée de la fabrication du papier.

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