Process for coating particles with metal compounds

C - Chemistry – Metallurgy – 04 – B

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C04B 20/10 (2006.01) C04B 35/628 (2006.01) C04B 41/45 (2006.01) C04B 41/81 (2006.01) C09C 3/00 (2006.01)

Patent

CA 2007722

- 1 - ABSTRACT Process for coating discrete particles (preferably ceramic particles) with metal compounds, namely metal oxides and metal nitrides. The process comprises forming a solution of an organometallic compound in a substantially anhydrous solvent that is substantially immiscible with water at ambient temperature, coating the particles with the solution and maintaining the particles substantially separate from each other while removing the solvent from the coating solution, e.g. by atomizing a slurry of the particles and the solution into a volume of heated gas. The resulting particles coated with the organometallic compound are then heated to a temperature at which the organometallic compound is converted to the corresponding metal oxide. If the final coating is to consist of a metal nitride, a carbon precursor (e.g. petroleum pitch) is also dissolved in the anhydrous solvent before the particles are coated, and then the oxide formed in the heating step is converted to the nitride by further heating at high temperature in the presence of nitrogen or a nitrogen precursor. The process is capable of producing ceramic particles coated with a uniform, continuous, non-porous layer of metal oxide or nitride suitable for use, for example, as reinforcements for ceramic or metallic composite materials.

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