C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/490.5
C07C 69/33 (2006.01) C07C 67/38 (2006.01)
Patent
CA 1156670
- 20 - PROCESS FOR CONTINUOUS PRODUCTION OF FULL ESTER OF POLYOLS ABSTRACT OF DISCLOSURE . Full esters of polyols selected from pentaerythritol and polypentaerythritols are continuously produced by (i) continuously introducing a solution of the polyols in pyridine bases, olefins having at least 4 carbon atoms in an amount of at least 0.4 equivalent per 1.0 equivalent of the hydroxyl group in the polyols, a catalyst containing cobalt carbonyls and pyridine bases, and carbon monoxide, into a reaction zone from one end thereof in such an amount of the pyridine bases as is within the range of from 40 to 70% by weight based on the total amount of the pyridine bases, the polyols and the olefins; (ii) introducing an additional amount of the olefins into at least one middle portion of the reaction zone, and; (iii) continuously withdrawing the resultant reaction mixture from the other end of the reaction zone.
329372
Isa Hiroshi
Karube Kenji
Nakayama Junichi
Lion Fat And Oil Co. Ltd. (the)
Mitsubishi Chemical Industries Limited
Ridout & Maybee Llp
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