Process for converting alcohols to carbonyl compounds

Details Process for converting alcohols to carbonyl compounds Process for converting alcohols to carbonyl compounds

C - Chemistry, Metallurgy

07

C

C07C 45/39 (2006.01) B01J 31/18 (2006.01) C07D 315/00 (2006.01) C07F 1/00 (2006.01)

Patent

CA 2480788

The present invention provides a process for selectively converting dihydroxy- or-polyhydroxy alcohols into carbonyl compounds using dioxygen (O2) as oxidant in the presence of a catalytic system comprising (1) a copper salt, a copper salt containing a heterocyclic ligand or a copper complex salt, and (2) a base.

Cette invention se rapporte à un procédé servant à convertir sélectivement des alcools dihydroxy ou polyhydroxy en composés carbonyle en utilisant du dioxygène (O¿2?) comme oxydant en présence d'un système catalytique comprenant (1) un sel de cuivre, un sel de cuivre contenant un ligand hétérocyclique ou un sel de complexe de cuivre, et (2) une base.

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