Process for converting carbon monoxide and water in a...

C - Chemistry – Metallurgy – 01 – B

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C01B 3/48 (2006.01) B01J 8/04 (2006.01) B01J 19/00 (2006.01) B01J 21/06 (2006.01) B01J 23/40 (2006.01) B01J 35/00 (2006.01) B01J 35/10 (2006.01) C01B 3/38 (2006.01)

Patent

CA 2372543

A process for converting carbon monoxide and water in a reformate stream into carbon dioxide and hydrogen comprising: generating a reformate by reacting a hydrocarbon via partial oxidation, steam reforming, or both, including autothermal reforming; and promoting a water gas shift in the reformate in the presence of a platinum group metal selected from the group consisting of platinum, palladium, iridium, osmium, rhodium and mixtures thereof, supported on zirconium oxide. The platinum group metal advantageously may be supported directly on a monolithic substrate composed of zirconium oxide.

La présente invention concerne un procédé permettant de convertir le monoxyde de carbone et l'eau d'un flux de reformat en dioxyde de carbone et en hydrogène, lequel procédé consiste à produire un reformat en faisant réagir un hydrocarbure via oxydation partielle ou reformage à la vapeur, ou ces deux réactions combinées y compris le reformage autothermique, et à provoquer une conversion catalytique dans le reformat en présence d'un métal du groupe platine choisi dans le groupe composé du platine, du palladium, de l'iridium, de l'osmium, du rhodium et de mélanges de ces derniers, supporté sur de l'oxyde de zirconium. Pour un meilleur résultat, le métal du groupe platine est supporté directement sur un substrat monolithique composé d'oxyde de zirconium.

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