Process for dehalogenation of organic compounds

C - Chemistry – Metallurgy – 07 – C

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C07C 1/26 (2006.01) C07C 15/04 (2006.01) C07C 15/14 (2006.01) C07C 25/18 (2006.01) C10M 175/00 (2006.01) A62D 3/00 (2006.01)

Patent

CA 2024107

Organohalides are dehalogenated by bringing an organohalide or a mixture of two or more organohalides into contact with an alkali hydroxide in an alcoholic solution and in the presence of a catalytically effective amount of a heterogeneous transfer hydrogenolysis catalyst. The process can be carried out at relatively low temperatures (50° - 150°C )and at low pressures.

Des halogénures organiques sont déshalogénés en mettant un halogénure organique ou un mélange de deux halogénures organiques ou plus en contact avec un hydroxyde alcalin dans une solution alcoolique et en présence d'une quantité catalytiquement efficace d'un catalyseur d'hydrogénolyse de transfert hétérogène. Le procédé peut être réalisé à des températures relativement faibles (50-150 degrés C) et à des pressions faibles.

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