C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/530.6
C07C 303/44 (2006.01) C07B 63/00 (2006.01) C07C 7/00 (2006.01) C07C 7/10 (2006.01) C07C 7/148 (2006.01) C07C 9/00 (2006.01) C07C 9/14 (2006.01) C07C 9/15 (2006.01) C07C 9/22 (2006.01) C07C 39/04 (2006.01) C07C 303/04 (2006.01) C07C 303/28 (2006.01) C07C 309/02 (2006.01) C07C 309/03 (2006.01) C07C 309/04 (2006.01) C07D 303/44 (2006.01) C10G 21/06 (2006.01) C10G 73/02 (2006.01) C10G 73/06 (2006.01) C10G 73/38 (2006.01) C11D 3/34 (2006.01)
Patent
CA 1296359
"PROCESS FOR EXTRACTING PARAFFINS FROM THEIR MIXTURES WITH ALKANESULPHONIC ACIDS" ABSTRACT OF THE DISCLOSURE In preparing alkanesulphonic acids by sulphoxidation of n- paraffins containing between 12 and 18 carbon atoms, using UV radiation to initiate the reaction (light-water process), a mixture is obtained which spontaneously allows a substantial part of the unconverted n-paraffins to separate from a mixture containing the alkanesulphonic acids together with water, sulphuric acid and n-paraffins. The aforesaid mixture is fed with one or more alcohols having four or less than four carbon atoms, preferably isopropanol, to form a two-phase mixture. The two-phase mixture is extracted with supercritical CO2, which extracts the n-paraffins, these being recycled to the sulphoxidation process. The paraffin- free product is suitable for preparing alkanesulphonates of the desired type by neutralisation with suitable bases.
542773
Carrillo Gerardo
Faggian Lucio
Franco Cosimo
Enichem Augusta S.p.a.
Eniricerche S.p.a.
Robic
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