Process for fluorinating chlorofluoro telomers

C - Chemistry – Metallurgy – 07 – C

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260/656.2

C07C 19/08 (2006.01) C08F 8/20 (2006.01)

Patent

CA 1236489

PROCESS FOR FLUORINATING CHLOROFLUORO TELOMERS ABSTRACT An improved process for fluorinating chlorofluoro telomers, and particularly telomers of chlorotrifluoro- ethylene, is disclosed. The process of the present invention comprises reacting the crude telomer with a fluorlnating agent in the presence of a catalytic amount of a fluorination catalyst. The fluorinating agent preferably comprises chlorine trifluoride (C1F3) and the fluorination catalyst comprises a transition metal halide selected from the group consisting of halides of iron, nickel, chromium, and mixtures thereof. The process is preferably conducted at a tempera- ture in the range of from about 120°C to about 250°C and continues until the desired degree of fluorination is achieved.

427184

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