Process for hydrogenolysis of carboxylic acid esters

Details Process for hydrogenolysis of carboxylic acid esters Process for hydrogenolysis of carboxylic acid esters

C - Chemistry, Metallurgy

07

C

260/637.8

C07C 29/136 (2006.01) B01J 23/80 (2006.01) C07C 29/149 (2006.01) C07C 29/17 (2006.01) C07C 31/02 (2006.01)

Patent

CA 1229096

ABSTRACT OF THE DISCLOSURE Catalytic hydrogenolysis of carboxylic acid esters to produce alcohols is conducted in the vapor phase using hydrogen gas and a catalyst comprising a reduced mixture of copper oxide and zinc oxide, at temperatures at from about 75°C to about 300°C and pressures from about 0.1 kg/cm2 to about 100 kg/cm2 absolute. The ester may be essentially any of a vaporisable ester. The process is preferably carried out in a continuous manner, using a solid pelletized catalyst.

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