Process for improving the adhesion of polymeric materials to...

C - Chemistry – Metallurgy – 23 – C

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C23C 22/78 (2006.01) B05D 3/10 (2006.01) C09K 3/14 (2006.01) C23C 22/40 (2006.01) C23C 22/52 (2006.01) C23F 1/18 (2006.01) H05K 3/38 (2006.01)

Patent

CA 2407280

A composition and process are described which are useful in treating metal surfaces, which composition comprises an oxidizer, an acid, a corrosion inhibitor, an organic nitro compound and, optionally, a benzotriazole with an electron withdrawing group in the 1-position which electron withdrawing group is a stronger electron withdrawer than a hydrogen group, optionally, a source of adhesion enhancing species selected from the group consisting of molybdates, tungstates, tantalates, niobates, vanadates, isopoly or heteropoly acids of molybdenum, tungsten, tantalum, niobium, vanadium, and combinations of any of the foregoing and optionally but preferably a source of halide ions. The composition and process are useful in increasing the adhesion of metal surfaces to polymeric substances and in preserving said adhesion through temperature variation.

Cette invention concerne une composition et un procédé convenant bien pour le traitement de surfaces métalliques. Cette composition comprend un oxydant, un acide, un inhibiteur de corrosion, un composé nitro organique et, éventuellement, un benzotriazole avec un groupe suppresseur d'électron en position 1, lequel groupe suppresseur est un suppresseur d'électron plus puissant qu'un groupe hydrogène, éventuellement une source d'adhérence, en particulier d'espèces prises dans le groupe composé de molybdates, tungstates, tantalates, niobates, vanadates, isopoly or hétéropoly acides de molybdène, tungstène, tantale, niobium, vanadium, et de combinaisons des composés et corps susmentionnés et éventuellement, mais de préférence, une source d'ions halides. La composition et le procédé selon l'invention favorisent l'adhésion de surfaces métalliques sur des substances polymères indépendamment des variations de température.

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