Process for increasing the efficiency of a pre- polymerized...

C - Chemistry – Metallurgy – 08 – F

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C08F 10/00 (2006.01) B01J 19/18 (2006.01) C08F 4/60 (2006.01) C08F 10/06 (2006.01) C08F 110/06 (2006.01)

Patent

CA 1274945

ABSTRACT The invention provides a process for pre-polymerizing olefin polymerization catalysts and a process for increasing the efficiency of pre-polymerized olefin polymerization catalysts. In one process of this invention an olefin monomer is added to a fluid carrier stream containing an olefin polymerization catalyst. The carrier stream containing the monomer and the catalyst is passed through an elongated tubular reactor at a flow rate sufficient to provide a residence time in the tubular reactor of less than 1 minute and under temperature conditions to pre-polymerize the catalyst within the tubular reactor without plugging of the reactor. In another process of this invention a pre-polymerized catalyst is contacted with a cocatalyst or a mixture of cocatalyst and an electron donor prior to introducing the catalyst into a polymerization reaction zone.

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