Process for initiating a highly selective ethylene oxide...

C - Chemistry – Metallurgy – 07 – D

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C07D 301/10 (2006.01)

Patent

CA 2700776

A process for initiating a highly selective ethylene oxide catalyst is provided in which the highly selective ethylene oxide catalyst is operated first as a 'standard' Ag-based catalyst (e.g., a catalyst that contains only silver and alkali metal, especially cesium). Moreover, the inventive initiation procedure is more efficient when the concentration of carbon dioxide in the feed is higher than 6 vol. %, and even more efficient when the concentration of carbon dioxide in the feed is higher than 10 vol. %, of the feed mixture during the initiation period.

La présente invention a pour objet un procédé d'initialisation d'un catalyseur d'oxyde d'éthylène hautement sélectif dans lequel le catalyseur d'oxyde d'éthylène hautement sélectif fonctionne d'abord comme un catalyseur = classique = à base d'Ag (par exemple,un catalyseur qui contient seulement de l'argent et un métal alcalin, spécialement du césium). En outre, la procédure d'initialisation de l'invention est plus efficace lorsque la concentration du dioxyde de carbone dans la charge est supérieure à 6 % en volume, et même davantage efficace lorsque la concentration du dioxyde de carbone dans la charge est supérieure à 10 % en volume, du mélange de la charge au cours de la période d'initialisation.

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