Process for making propargyl ether of bisphenols

C - Chemistry – Metallurgy – 07 – C

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260/645.1, 260/6

C07C 41/16 (2006.01) C07C 43/215 (2006.01) C07C 45/71 (2006.01) C07C 49/84 (2006.01)

Patent

CA 1318688

ABSTRACT A process for preparing an aromatic propargyl ether, preferably bispropargyl ether, from hydroxyaromatic compounds comprising vigorously stirring a propargyl halide, preferably propargyl chloride, with a hydroxyaromatic compound, such as bisphenol A, in an aqueous sodium hydroxide solution at a temperature of from 0°C to 100°C, in the presence of a phase transfer catalyst such as tetrabutylammonium bromide. The mixture id then filtered to recover a solid product. That product is washed with water and propanol. This process provides a product having greater than 95 percent purity in yields ranging from 85 to 97 percent of theoretical.

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