C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/645.1, 260/6
C07C 41/16 (2006.01) C07C 43/215 (2006.01) C07C 45/71 (2006.01) C07C 49/84 (2006.01)
Patent
CA 1318688
ABSTRACT A process for preparing an aromatic propargyl ether, preferably bispropargyl ether, from hydroxyaromatic compounds comprising vigorously stirring a propargyl halide, preferably propargyl chloride, with a hydroxyaromatic compound, such as bisphenol A, in an aqueous sodium hydroxide solution at a temperature of from 0°C to 100°C, in the presence of a phase transfer catalyst such as tetrabutylammonium bromide. The mixture id then filtered to recover a solid product. That product is washed with water and propanol. This process provides a product having greater than 95 percent purity in yields ranging from 85 to 97 percent of theoretical.
568197
Dirlikov Stoil K.
Inbasekaran Muthiah N.
Dirlikov Stoil K.
Inbasekaran Muthiah N.
Smart & Biggar
The Dow Chemical Company
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