Process for making silicon nitride whisker

C - Chemistry – Metallurgy – 01 – B

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C01B 21/068 (2006.01) C30B 25/00 (2006.01)

Patent

CA 2000457

Silica powder or a mixture of silica powder and silicon nitride whisker are heated at a temperature ranging from 800°C to 1,700°C in a gaseous mixture of ammonia gas (NH3) and hydrocarbon gas (CmHn) so as to produce silicon nitride whisker. The gaseous mixture flows at the rate of 10 mm/sec or less. The ratio of the ammonia to the hydrocarbon expressed as NH3/CH4 ranges from 0.5:1 to 2000:1 by volume. The silica powder is preferably mixed with at least one of six catalysts: transition metals; alkali metals: alkaline earth metals: halides of transition metals; halide; of alkali metals; and alkaline earth metals. One mol part of the silica powder is mixed with 0.001 - 1.0 mol part of the catalyst.

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