Process for ortho- and para-alkylating diphenylamines

C - Chemistry – Metallurgy – 07 – C

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C07C 209/68 (2006.01) C07C 211/54 (2006.01)

Patent

CA 1283126

ABSTRACT OF THE DISCLOSURE Ortho-para-alkylated diphenylamines are prepared utilizing an improved, one-stage process wherein the diphenylamines are ortho-alkylated by reaction with a first olefin in the presence of an aluminum complex as the catalyst, and are subsequently para-alkylated by reaction with a second olefin using a Friedel-Crafts aluminum catalyst. The para-alkylation is carried out without prior isolation or solvent washing of the ortho-alkylated diphenylamine intermediates.

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