Process for oxidating paraffinic compounds

C - Chemistry – Metallurgy – 07 – C

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260/487, 260/582

C07C 29/48 (2006.01) C07C 31/125 (2006.01) C07C 35/08 (2006.01) C07C 45/28 (2006.01) C07C 49/04 (2006.01) C07C 49/403 (2006.01)

Patent

CA 2022241

Process for oxidating paraffinic compounds in order to yield the corresponding alcoholic and/or ketonic compounds, which process consists of of reacting said paraffins with an aqueous solution of hydrogen peroxide, possibly dissolved in a solvent, by operating at a temperature comprised within the range of from 0°C to 100°C, in the presence of a titanium-silicalite of formula pHMO2.qTiO2.SiO2 wherein M is a metal selected from among aluminum, gallium and iron, p is comprised within the range of from 0 to 0.05 and q is comprised within the range of from 0.0001 to 0.04, and the H+ of HM0z can be at least partially replaceable or replaced by cations.

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