Process for polymerising or oligomerising a hydrocarbon

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 2/36 (2006.01) C07C 2/12 (2006.01) C07C 11/107 (2006.01)

Patent

CA 2705154

A process (10) for polymerizing or oligomerising a hydrocarbon includes feeding at a low level a liquid hydrocarbon reactant (32) into a bulk liquid phase (14) comprising polymeric or oligomehc product admixed with a catalyst. The liquid hydrocarbon reactant is allowed to vapouhse to form bubbles rising through the bulk liquid phase (14) and to polymerise or oligomerise to form the polymeric or oligomeric product, with the rising bubbles creating turbulence in the bulk liquid phase (14), thereby mixing the bulk liquid phase (14). Gaseous components (26) comprising any unreacted vapouhsed hydrocarbon reactant and any gaseous product that may have formed are withdrawn from a head space above the bulk liquid phase (14). Liquid phase from the bulk liquid phase (14) is withdrawn (18) to maintain the bulk liquid phase (14) at a desired level.

L'invention porte sur un procédé (10), pour polymériser ou oligomériser un hydrocarbure, qui comprend l'introduction à un faible niveau d'un réactif hydrocarboné liquide (32) dans une phase liquide en vrac (14) comportant un produit polymère ou oligomère mélangé avec un catalyseur. Le réactif hydrocarboné liquide est amené à se vaporiser pour former des bulles montant à travers la phase liquide en vrac (14) et à se polymériser ou s'oligomériser pour former le produit polymère ou oligomère, les bulles montantes créant une turbulence dans la phase liquide en vrac (14), mélangeant ainsi la phase liquide en vrac (14). Des composants gazeux (26) comportant tout réactif hydrocarboné vaporisé n'ayant pas réagi et tout produit gazeux qui peut avoir été formé sont éliminés d'un vide au-dessus de la phase liquide en vrac (14). La phase liquide provenant de la phase liquide en vrac (14) est évacuée (18) pour maintenir la phase liquide en vrac (14) au niveau voulu.

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