C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
252/109, 402/566
C08F 4/642 (2006.01) C08F 10/02 (2006.01)
Patent
CA 1338033
Ethylene homopolymers and ethylene copolymers with alpha-(C3-C10)-olefins are obtained by polymerizing the monomers with a polymerization catalyst formed by: a) an alkyl-aluminum; and b) a modified solid catalyst component obtained by treating with a Lewis' base a non-modified solid component to be defined by means of the following formula, expressed as atomic proportions: Ti (1), Hf (0.5-3), Si (1- 6), Mg (0.5-15), Al (0.5-15), X (20-60), ROH (1-10) wherein: X represents either chlorine and bromine, and R represents an either linear or branched alkyl radical of from 1 to 6 carbon atoms. The catalyst is particularly useful for controlling the molecular weight and the molecular weight distribution of ethylene homopolymers and copolymers.
612141
Barazzoni Lia
Ciardelli Francesco
Ferrero Cesare
Invernizzi Renzo
Malquori Stefano
Enichem Anic S.p.a.
Robic
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