Process for polymerizing olefinic monomers which...

Details Process for polymerizing olefinic monomers which... Process for polymerizing olefinic monomers which...

C - Chemistry, Metallurgy

08

F

402/422, 402/504

C08F 2/16 (2006.01) C08F 2/00 (2006.01) C08F 14/06 (2006.01) C23F 14/00 (2006.01)

Patent

CA 1044845

ABSTRACT OF THE DISCLOSURE There is disclosed a process for polymerizing olefinic monomers, such as vinyl halides, vinylidene halides and vinyli- dene monomers having at least one terminal CH2=C< grouping, and mixtures thereof whereby polymer building-up on the inner surfaces of the reactor is substantially eliminated. The process is carried out in a reaction vessel the inner surfaces of which are coated with a coating composition containing, as a primary ingredient, polyethyleneimine and wherein the polymerization medium in contact with said coated surfaces contains a water- soluble divalent tin salt as a water-phase polymerization in- hibitor. The coating and inhibitor produce a synergistic effect. -1-

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