Process for preparation of alcohols by hydration of olefins

C - Chemistry – Metallurgy – 07 – C

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260/639.4

C07C 31/02 (2006.01) C07C 29/04 (2006.01) C07C 45/00 (2006.01)

Patent

CA 1212384

PROCESS FOR PREPARATION OF ALCOHOLS BY HYDRATION OF OLEFINS ABSTRACT OF THE DISCLOSURE Olefins are hydrated to the corresponding alcohols in the presence of at least one crystalline alumino- silicate selected from offretite, ferrierite and erionite. The offretite, ferrierite and erionite are preferably characterized by Xray diffraction patterns shown in Tables 1 and 7; Tables 2, 8 and 9; and Table 3, respectively. At least a part of the exchangeable cations in the offretite, ferrierite and erionite may be exchanged with at least one cation selected from a hydrogen ion, an alkaline earth metal ion and a rare earth metal ion. Furthermore, at least a part of the exchangeable cations in the erionite may be exchanged with an ammonium ion and/or an alkali metal ion.

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