C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/642.4
C07C 409/08 (2006.01)
Patent
CA 1113506
ABSTRACT OF THE DISCLOSURE An improved process for the preparation of an aromatic hydroperoxide by oxidizing a hydroxyalkyl- substituted aromatic compound having at least one hydroxy- alkyl group directly bonded to an aromatic ring carbon of the aromatic compound and being represented by the formula Image wherein R1 and R2 each are a lower alkyl group, with hydrogen peroxide in the presence of an acid catalyst in a heterogeneous system of a water-immiscible inert aromatic hydrocarbon solvent at a reaction temperature of up to about 70°C while removing by-product water as an azeotrope with the aromatic hydrocarbon solvent in the oxidation system; characterized in that said oxidation is carried out while feeding a vapor of a water-immiscible inert aromatic hydrocarbon solvent having a temperature higher than the reaction temperature but not exceeding about 90°C into a liquid phase of the oxidation system.
337725
Hashimoto Isao
Imai Ichiro
Nakagawa Hiroaki
Suzuki Keiji
Mitsui Chemicals Incorporated
Smart & Biggar
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