Process for preparation of condensed alcohols by alkoxide...

C - Chemistry – Metallurgy – 07 – C

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260/639

C07C 29/34 (2006.01) C07C 31/125 (2006.01)

Patent

CA 2034762

ABSTRACT OF THE DISCLOSURE Condensed dimer alcohols, also known as Guerbet alcohols, are prepared using metal alkoxide as the catalyst by reacting alcohol with saturated or unsaturated aldehyde or allyl alcohol, or mixtures thereof, at 100°C-220°C and removing water as it is formed during the reaction. Dimer alcohols are prepared in high yields without the need for a transition metal catalyst.

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