C - Chemistry – Metallurgy – 07 – D
Patent
C - Chemistry, Metallurgy
07
D
C07D 211/94 (2006.01)
Patent
CA 2506407
The present invention relates to processes for preparing 4-substituted 2,2,6,6-tetramethylpiperidin-N-oxy compounds [II] or mixtures of [II] and 4- substituted 2,2,6,6-tetramethylpiperidin-N-hydroxy compounds [III] Image where X+Y can be O or can represent a cyclic ketal with the radicals Image or can represent an open-chain ketal in which X= O-R and Y= O-R', where R and R' can be identical or different and can each be CH3, CH2-CH3, CH2-CH2-CH3, CH(CH3)-CH3, CH2-CH2-CH2-CH3 and CH2-CH(CH3)-CH3, by oxidizing corresponding 4-substituted 2,2,6,6-tetramethylpiperidines [I] Image by means of hydrogen peroxide in the presence of alkali metal hydrogencarbonate and/or ammonium hydrogencarbonate and in the presence or absence of a solvent, in which the reaction is carried out with the addition of Brönsted acids which have an acid strength greater than that of the hydrogencarbonate used.
Kuebelbaeck Thomas
Meyer Oliver
Osterholt Clemens
Poll Heinz-Guenter
Degussa Ag
Fetherstonhaugh & Co.
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