Process for preparing aldehydes

C - Chemistry – Metallurgy – 07 – C

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C07C 47/02 (2006.01) B01J 31/18 (2006.01) B01J 31/22 (2006.01) C07C 45/50 (2006.01) C07C 47/228 (2006.01) C07C 67/38 (2006.01) C07C 69/24 (2006.01) C07C 253/30 (2006.01) C07C 255/02 (2006.01)

Patent

CA 2165891

The invention relates to the hydroformylation of olefins and olefinically unsaturated compounds in the presence of cobalt or rhodium complexes which contain as complexing ligands heterocyclic carbenes and in addition, if desired, further ligands. The complexes have the formula: [L a M b X c] n (A) n' in which M rhodium or cobalt as a central atom, X is a monodentate or multidentate, charged or uncharged ligand bound to the central atom and L is a ligand, bound to the central atom, which is a monocarbene of the formulae Image or a dicarbene of the formulae Image where R1, R2, R3, R4, R5 and R6 are, for example, sulfonated or unsulfonated aliphatic or aromatic radicals.

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