Process for preparing .alpha.-olefins from light olefins

C - Chemistry – Metallurgy – 07 – C

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260/706.1

C07C 2/12 (2006.01) C07C 11/02 (2006.01)

Patent

CA 1269402

PROCESS FOR PREPARING ALPHA-OLEFINS FROM LIGHT OLEFINS ABSTRACT OF THE DISCLOSURE A process for preparing alpha-olefins by converting a feed of one or more lower olefins in the presence of a medium pore crystalline silicate zeolite catalyst to produce a mixture of higher olefins, contacting the higher olefins with an alpha-olefin in the presence of a metathesis catalyst to produce a mixture of alpha-olefins having a different carbon number than the feed, separating the mixture into at least two fractions, a lower alpha-olefin fraction and a higher alpha-olefin fraction and, recycling at least some of the lower alpha-olefin fraction as feed for the process.

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