Process for preparing aromatic carboxylic acids with...

C - Chemistry – Metallurgy – 07 – C

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C07C 51/265 (2006.01) C01B 7/09 (2006.01) C07C 29/124 (2006.01) C07C 63/26 (2006.01)

Patent

CA 2320206

Processes are disclosed for recovery of hydrogen bromide from one or more alkyl bromide compounds by hydrolyzing the alkyl bromide compounds to hydrogen bromide and corresponding alcohols, and simultaneously separating at least the alcoholic products of hydrolysis from aliphatic monocarboxylic acid solvent component. Also disclosed are process for preparing aromatic carboxylic acids by the exothermic, liquid-phase oxidation of an aromatic feedstock compound wherein the energy produced by the exothermic oxidation is efficiently recovered, and uses of water produced during the preparation of aromatic carboxylic acids are efficiently integrated into the process.

L'invention concerne des procédés de récupération de bromure d'hydrogène à partir d'un ou de plusieurs composés de bromure d'alkyle, ces procédés consistant à hydrolyser les composés de bromure d'alkyle pour obtenir du bromure d'hydrogène et des alcools correspondants, et simultanément à séparer au moins les produits alcooliques de l'hydrolyse, à partir du solvant de l'acide monocarboxylique aliphatique. L'invention concerne également un procédé de préparation d'acides carboxyliques aromatiques, par oxydation exothermique en phase liquide d'une charge aromatique dans laquelle l'énergie produite par cette oxydation est récupérée de manière efficace; elle concerne encore l'intégration dans le procédé des utilisations de l'eau produite pendant la préparation des acides carboxyliques aromatiques.

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