Process for preparing aromatic hydroxycarboxylic acids

C - Chemistry – Metallurgy – 07 – C

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C07C 65/01 (2006.01) C07C 51/15 (2006.01)

Patent

CA 2124055

Abstract Process for preparing aromatic hydroxycarboxylic acids A process for preparing aromatic hydroxycarboxylic acids or di-salts thereof by reaction of alkali metal phenol- ates or naphtholates with carbon dioxide, in the presence or absence of a further alkali metal salt, which com- prises introducing the solid phenolate or naphtholate starting materials and, if desired, the alkali metal salt into the reaction mixture batchwise or continuously, separately or together, in the form of a dispersion in an inert organic liquid. The process of the invention makes possible the prepara- tion of aromatic hydroxycarboxylic acids in good yields and with high chemical selectivity. Additional measures for increasing the selectivity, as are described for the Kolbe-Schmitt reaction in, for example, EP-A 0 053 824, EP-A 0 081 753 and EP-A 0 254 596, can be omitted.

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