Process for preparing bimodal or multimodal polymers of...

C - Chemistry – Metallurgy – 08 – F

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402/423, 400/490

C08F 8/04 (2006.01) C08F 36/04 (2006.01)

Patent

CA 1145883

ABSTRACT OF THE DISCLOSURE: A process of preparing a bimodal or multimodal homopolymer of a conjugated diene or a bimodal or multi- modal copolymer of a conjugated diene with another conjugated diene or with a vinyl aromatic compound consists in polymer izing the monomer(s) in a reaction medium at a temperature of between 20°C. and 200°C. in the presence of a catalytic system comprising an organolithium initiator, a barium, strontium or calcium compound, and an organometallic com- pound of a metal of group 2B or 3A of the periodic classifi- cation of elements of the Mendeleev Table and adding hydrogen as a modifying agent to the reaction medium during the course of the polymerization reaction.

375107

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