C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/529.6
C07C 51/12 (2006.01) C07C 53/08 (2006.01)
Patent
CA 2028821
2028821 9011991 PCTABS00002 A process for preparing a carboxylic acid having (n+1) carbon atoms (e.g. acetic acid) from an alcohol having n carbon atoms (e.g. methanol) by liquid phase, rhodium catalysed carbonylation is provided. The process is characterised by using a catalyst stabiliser selected from certain classes of imidazolium iodides, alkyl substituted pyridinium iodides and hydroxypyridinium iodides. Most preferred are those derived from the amines 2-ethyl-4-methylimidazole, 4-methylimidazole, 4-ethylpyridine, 4-t-butylpyridine and 3,4-lutidine by quaternisation with a methyl group.
Beevor Robert G.
Gulliver David J.
Bp Chemicals Limited
Fetherstonhaugh & Co.
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